Publication

Remarkable Solvent Effects of Structurally Diverse Alcohols on Nucleophilic Displacement Reactions with Halide Ions

조회수 : 28 등록일 : 2018.08.07 00:00

저자 : Chi, DY (Chi, DaeYoon)[ 2,4 ]
출처 : BULLETIN OF THE KOREAN CHEMICAL SOCIETY
출판일 : 2018.07.01



Remarkable Solvent Effects of Structurally Diverse Alcohols on Nucleophilic Displacement Reactions with Halide Ions


Moon, BS (Moon, Byung Seok)1 ] Lee, BS (Lee, Byoung Se)2 ] Chu, SY (Chu, So Young)2 ] Kim, DW (Kim, Dong Wook)3 ] Chi, DY (Chi, DaeYoon)2,4 ]


[ 1 ] Seoul Natl Univ, Dept Nucl Med, Bundang Hosp, Seongnam 13620, South Korea
[ 2 ] FutureChem Co Ltd, Res Inst Labeling, Seoul 01811, South Korea
[ 3 ] Inha Univ, Dept Chem, Incheon 22212, South Korea
[ 4 ] Sogang Univ, Dept Chem, Seoul 04107, South Korea 



Solvent effects on nucleophilic displacement reactions of alkyl mesylates with halide ions were investigated in a series of protic alcohol solvents. In consideration of Hughes and Ingold's principle, the reaction rates were found to correlate well with the normalized solvent polarities (urn:x-wiley:12295949:media:bkcs11496:bkcs11496-math-0001) in all halide reactions.





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