Publication

Non-native transition metal monoxide nanostructures: unique physicochemical properties and phase transformations of CoO, MnO and ZnO

조회수 : 111 등록일 : 2017.04.26 00:00

저자 : Seo, WS (Seo, Won Seok)
출처 : NPG ASIA MATERIALS
출판일 : 2017.03.01
 
 
Non-native transition metal monoxide nanostructures: unique physicochemical properties and phase transformations of CoO, MnO and ZnO
 
 
Nam, KM (Nam, Ki Min)[ 1 ] ; Seo, WS (Seo, Won Seok)[ 2 ] ; Song, H (Song, Hyunjoon)[ 3 ] ; Park, JT (Park, Joon Taik)[ 3 ]
 
 
[ 1 ] Mokpo Natl Univ, Dept Chem, Jeonnam 1666 Yeongsan Ro, Muan Gun, Jeonnam, South Korea
[ 2 ] Sogang Univ, Dept Chem, Seoul 04107, South Korea
[ 3 ] Korea Adv Inst Sci & Technol, Dept Chem, 291 Daehak Ro, Daejeon 34141, South Korea
 
 
The discovery of unprecedented, non-native phases of transition metal oxides is a fascinating theme in materials chemistry, including the development of new synthetic strategies with excellent size-and phase-selectivity, and elucidation of their unique physicochemical properties. Most of the first-row transition metal monoxides, such as MnO, FeO, CoO and NiO, are known to exist in a cubic phase, but only ZnO adopts a hexagonal structure. This review summarizes recent results on the syntheses and characterization of the non-native phases of h-CoO, h-MnO and c-ZnO transition metal monoxides, compared to their native phases. The investigation of the size-and phase-selective synthetic methods, formation mechanism and unique physicochemical properties of non-native transition metal monoxides would have an enormous impact on materials chemistry and open a promising avenue for magnetic, electronic and spintronic applications.
 
 
 
 
 
 
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